Multispectral imaging of Wilfred/a’s cartonnage

E12328B_4viewsWhat you see above are 4 different images of our mummy Wilfred/a’s cartonnage. Each image represents a different way of looking at the cartonnage, and assists us in better understanding this object. But what are we seeing in these images, and how did we produce them? (If you have been following this blog, or our museum blog, these types of images may be familiar to you, since we have used these techniques to look at other objects, including a painted wooden shabti box. But every object is different, and in this case, I’ve learned something new that I’ve never seen before, so read on to learn more!)

Let’s start with the image in the upper left – this is easy.

E12328B_visible01_compressed

Visible image. Captured with a Nikon D5200, modified by replacing the hot mirror filter with a glass custom full spectrum filter, with a B+W UV-IR-cut filter & incandescent photo light source.

This is a photograph taken in normal (visible) light with a digital camera. This image represents what you see when you look at the object here in the Artifact Lab. We see that the surface of the cartonnage has a design painted in many different colors, and that there are some residues on the painted surface in areas. There is a lot that we can learn about this object just by looking at it in visible light, but what we cannot do is confidently identify the pigments used. So in this case, multispectral imaging comes in very handy. Let’s take a look at the next image.

E12328B_IR01_compressed

Visible induced IR luminescence image. Captured with Nikon D5200 modified full spectrum camera, #87C filter, Crimescope 600nm light source.

This is an image of the exact same view of the object, but it was captured using our modified digital camera with a #87C IR filter, using our SPEX Mimi Crimescope with the 600nm filter as a light source. With this technique, we can clearly identify that Egyptian blue was used in the areas that appear bright white, because these areas are showing visible-induced IR luminescence (in other words, they emit infrared light when excited with visible light). No other pigment used by the ancient Egyptians has this property, so we can say with certainty that these areas are painted with Egyptian blue. To better visualize these areas (since the rest of the image is nearly black) we can use the image captured in visible light and the above image to create a false color image.

False color image of the cartonnage created in Photoshop, where the areas painted with Egyptian blue appear red.

False color image of the cartonnage created in Photoshop, where the areas painted with Egyptian blue appear red.

The false color image shows us the luminescent (Egyptian blue) areas in red. If you look closely, you’ll be able to see that the red areas are slightly shifted, due to the fact that we probably bumped the camera in between shots. But you get the idea.

Finally, I wanted to see what we could learn about the cartonnage by looking at it under other wavelengths of light with the Crimescope. I was expecting that we’d probably be able to better visualize the old adhesive used to join the cartonnage fragments in the past, and maybe better understand the residues on the surface. But when we looked at it with the 300-400nm filter (with a peak emission of 365nm), this is what we saw:

UV visible fluorescence image, captured with a Nikon D5200 modified full spectrum camera with B+W UV-IR-cut filter, using the Mini Crimescope 300-400nm filter.

UV visible fluorescence image. Captured with a Nikon D5200 modified full spectrum camera with B+W UV-IR-cut filter, using the Mini Crimescope 300-400nm filter.

In this image, the areas that stand out the most are the areas fluorescing a bright orange-pink color, which appear pink in visible light. I had never seen this before and wasn’t exactly sure what this meant, but after looking into it a bit, I believe that this fluorescence indicates that the pink areas were painted with madder, a dyestuff obtained from the roots of the madder plant. Madder has been identified as being used in ancient Egypt to create pink pigments for painting, and is known for having a characteristic pinkish-orange UV fluorescence, which is how I would characterize what we’re seeing in the above image. There are other ways we could try to confirm this, but this was an exciting, and unexpected observation!

* Special thanks to conservation intern Yan Ling and Conservator Tessa de Alarcon for their help with capturing and processing these images.

Investigating the shabti box coating

Last month, I wrote about a new challenge in the lab, otherwise known as this shabti box and its associated shabtis:

front compressedAt first the box came into the lab with 3 shabtis, and then we found that there were 3 more in storage that may belong with the box as well. 4 of the shabtis are very similar in appearance whereas the other 2 are slightly different, so they may actually not be associated after all. Can you spot the 2 different shabtis?

2 of these things are not like the others...

2 of these things are not like the others…

All of these objects are made of wood, gesso, and paint. And as you can see, all of them have an orange-yellow coating on their surfaces. In my last post I posed the questions “what is this coating?” “is it an original varnish or is it a later restoration?”. My initial guesses were that it is either an original pistacia resin varnish, a later cellulose nitrate (or other old restoration adhesive) coating, or a combination of the two.

Well, there are several things we can do to try to answer these questions and to narrow down the possibilities. One of the first things I did was to look at these objects very carefully using our binocular microscope. I could see that the coating was applied unevenly, especially on the box, and that it is actively cracking and flaking. Another thing that I noticed was that there are areas on the box where the paint is lost and where the coating extends over the loss onto the gesso below.

A detail shot of one side of the shabti box - the yellow arrows are indicating areas where the coating extends over an area of paint loss onto the gesso.

A detail shot of one side of the shabti box – the yellow arrows are indicating where the coating extends over areas of paint loss onto the gesso.

Usually, this would indicate that the coating was applied after the damage occurred (so sometime after excavation, either in the field or soon after coming to the museum). So this is one clue, but doesn’t really answer my questions.

Next, I examined the shabti figures under ultraviolet (UV) light. In conservation we routinely use UV examination to characterize materials and to distinguish old restoration materials from original materials – for instance, shellac, used historically to repair objects, exhibits a characteristic bright orange fluorescence under UV. (For a great explanation of UV, along with some interesting images, check out this post on UV examination by my colleague Allison Lewis, conservator at UC Berkeley’s Phoebe A. Hearst Museum of Anthropology.)

The coating on the box and the shabtis has a yellow-orange appearance under UV – but not the bright orange that we expect to see from shellac.

shabti UV

4 shabti figures under UV light

So UV examination was helpful (it eliminated shellac as a possibility) but didn’t answer my questions either.

Next, I did a microchemical spot test on a couple of the previously detached flakes of the coating. We’ve used spot-testing before in the lab – the last time I wrote about it was in reference to the mystery fibers on Tawahibre’s coffin. In this case, I carried out a spot test for nitrates using diphenylamine (according to instructions in Material Characterization Tests for Objects of Art and Archaeology). Using this test, a sample containing nitrates will turn blue once a solution of diphenylamine/sulfuric acid is added. Below you can see the result of the test on one of the coating flakes from the shabti box (left) and the test on a control sample of cellulose nitrate adhesive (right).

Left: coating sample from the box after spot test (negative result) Right: control cellulose nitrate adhesive after spot test (positive result)

Left: coating sample from the box after spot test (negative result) Right: cellulose nitrate control after spot test (positive result)

Based on these results, it seems that the coating does not contain cellulose nitrate. This does not mean that the coating does not contain another recently-added adhesive. We have a few other ways of narrowing down the possibilities even further, and I will write about our continued work on this in my next post.

 

Happy Halloween from the Artifact Lab!

We’re celebrating Halloween tonight in the Artifact Lab as part of Yelp’s Night by the Nile event.

To get into the spirit, Lynn and I will be working late, in costume, and talking to guests about conservation and mummies.

We thought that for tonight’s event, it would be appropriate to lower the lights and do some ultraviolet (UV) examination of objects, and to talk about this process to those who visit the lab.

As we have explained in previous posts, visual examination is a critical first step of the conservation process. We can understand a lot about objects just by looking at them under good lighting and with magnification.

While most of our examination is initially carried out under visible light, we also use UV lamps (better known as black lights) to examine artifacts in order to make visible things that we cannot see otherwise. Examination of objects in the dark under UV allows us to see UV fluorescence of materials, and some materials exhibit unique or characteristic fluorescence. This often helps us characterize materials and to distinguish old restoration materials from original materials-for instance, shellac, used historically to repair objects, exhibits a characteristic bright orange fluorescence under UV.

For a great explanation of UV, along with some interesting images, check out this post on UV examination by my colleague Allison Lewis, conservator at UC Berkeley’s Phoebe A. Hearst Museum of Anthropology.

We’ll be sure to share any interesting images we capture tonight!